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And a lot of catalysts use so-called noble metals like platinum, palladium and rhodium, which are expensive. While the rising cost may undermine the economic incentive to use Dr. Hartings, of American University, believes that using abundant materials where possible could free up the scarcer materials for applications that truly require them. Chirik showed two small dishes of silicone flakes, used to make envelope glue. The process could herald a new era of flexible manufacturing technologies, while enabling companies to steer clear of scarce elements as prices rise or obtaining them becomes environmentally or geopolitically risky. There have been other hurdles. The molecules of the catalyst dissipate during the reaction. Today, Paul Chirik , a professor of chemistry at Princeton, has managed a new twist on the timeworn pursuit. They were indistinguishable. Chevron and Momentive, a silicone manufacturer, are financing Dr. Home Page World U.{/INSERTKEYS}{/PARAGRAPH} Merck is also a partner in the research. On a spring afternoon at the Princeton lab, a graduate student toiled away at a glovebox, a vacuum chamber that prevents the iron from rusting. Chirik worked on reactions that used iridium as a catalyst. Despite the cost and relative scarcity of precious metals β€” iridium, platinum, rhodium β€” we rely on them to manufacture products from denim to beer, pharmaceuticals to fuel cells. {PARAGRAPH}{INSERTKEYS}Throughout the centuries, alchemists tried in vain to transform common metals like iron and lead into precious ones like gold or platinum. Using cobalt, Dr. The elements are used as catalysts, substances that kick off or enable chemical reactions. Researchers in Dr. The ligand alters the number of electrons available to form bonds. One he made using iron, the other platinum. For instance, a solution containing platinum is used to make silicone emulsifiers, compounds that in turn feed products like makeup, cookware and glue. It also serves as a scaffold, giving the molecule shape. A pound of iron, meanwhile, costs about 50 cents. One product in development is a fuel-efficient tire that employs a new, cleaner process, with no byproducts, by using iron instead of platinum. The current method, the Haber-Bosch process, is so energy-intensive it accounts for 1 percent of all global energy use. Tiny amounts of the expensive metal are scattered in all these things; your jeans, for instance, contain unrecoverable particles of platinum. While important, those efforts are only part of the picture. Many drugmaking processes rely on rhodium or palladium. Chirik said. A vast majority of the chemicals we manufacture and then use to make other products require catalysts. This is why chemistry needs to be ahead of the curve. Rust is a potential downside of using iron in manufacturing, and controlling it could prove challenging and expensive. In addition to iron, Dr. We need to have adaptable solutions. As an undergraduate chemistry major, Dr. Chirik said, referring to the volume of chemicals involved when doing reactions on an industrial scale. Chirik, 39, has learned how to make iron function like platinum, in chemical reactions that are crucial to manufacturing scores of basic materials. The experience left him with the seed of an idea, he said. Hartings said. Chirik recalled.